Search results for "induced polarization"
showing 10 items of 23 documents
Time-domain-induced polarization: Full-decay forward modeling and 1D laterally constrained inversion of Cole-Cole parameters
2012
Time-domain-induced polarization has significantly broadenedits field of reference during the last decade, from mineralexploration to environmental geophysics, e.g., for clay and peatidentification and landfill characterization. Though, insufficientmodeling tools have hitherto limited the use of time-domaininducedpolarization for wider purposes. For these reasons, anew forward code and inversion algorithm have been developedusing the full-time decay of the induced polarization response,together with an accurate description of the transmitter waveformand of the receiver transfer function, to reconstruct thedistribution of the Cole-Cole parameters of the earth. The accuratemodeling of the tra…
Application of time domain induced polarization to the mapping of lithotypes in a landfill site
2012
A direct current (DC) resistivity and time domain induced polarization (TDIP) survey was undertaken at a decommissioned landfill site situated in Hørløkke, Denmark, for the purpose of mapping the waste deposits and to discriminate important geological units that control the hydrology of the surrounding area. It is known that both waste deposits and clay have clear signatures in TDIP data, making it possible to enhance the resolution of geological structures compared to DC surveys alone. <br><br> Four DC/TDIP profiles were carried out crossing the landfill, and another seven profiles in the surroundings provide a sufficiently dense coverage of the entire area. The whole dataset w…
Femtosecond time resolved coherent anti-Stokes Raman spectroscopy: Experiment and modelization of speed memory effects on H2-N2 mixtures in the colli…
2005
194317; With the aim of temperature diagnostic, femtosecond time-resolved CARS (coherent anti-Stokes Raman spectroscopy) is applied to probe H2 in H2-N2 mixtures. In a first part, a Lorentzian profile is used to model the femtosecond CARS response. A difference between the experimental broadening and the expected one is observed in the collision regime. The observed broadening increases strongly in an inhomogeneous way with respect to the perturber concentration. This is of considerable importance for temperature measurements. In a second part, we show that in the collision regime, this inhomogeneous broadening is due to the speed dependence of the collisional parameters and the memory effe…
Measurements of the induced polarization in the quasi-elastic A(e,e′p→) process in non-coplanar kinematics
2020
Abstract We report measurements of the induced polarization P → of protons knocked out from 2H and 12C via the A ( e , e ′ p → ) reaction. We have studied the dependence of P → on two kinematic variables: the missing momentum p miss and the “off-coplanarity” angle ϕ p q between the scattering and reaction planes. For the full 360° range in ϕ p q , both the normal ( P y ) and, for the first time, the transverse ( P x ) components of the induced polarization were measured with respect to the coordinate system associated with the scattering plane. P x vanishes in coplanar kinematics, however in non-coplanar kinematics, it is on the same scale as P y . We find that the dependence on ϕ p q is si…
Mapping of landfills using time-domain spectral induced polarization data: the Eskelund case study
2012
This study uses time-domain induced polarization data for the delineation and characterization of the former landfill site at Eskelund, Denmark. With optimized acquisition parameters combined with a new inversion algorithm, we use the full content of the decay curve and retrieve spectral information from time-domain IP data. Thirteen IP/DC profiles were collected in the area, supplemented by el-log drilling for accurate correlation between the geophysics and the lithology. The data were inverted using a laterally constrained 1D inversion considering the full decay curves to retrieve the four Cole-Cole parameters. For all profiles, the results reveal a highly chargeable unit that shows a ver…
Transmitter waveform and receiver transfer function modelling in time domain induced polarization
2012
SUMMARY In the computation of the forward response for Time Domain Induced Polarization the incomplete description of the transmitter waveform causes dramatic errors in the estimation of the magnitude and time characteristic of the IP phenomenon. Both the duration of the current pulse and the sequence of pulses used for the stacking procedure have a strong effect in the magnitude and shape of the IP decays. Furthermore, it is important to model low-pass filters of the receiver system, in order to extract all the information contained in the acquired data. For these reasons, a new 1D forward and inversion algorithms have been developed using the full time decay of the IP response and the rec…
Temperature measurement in gas mixtures by femtosecond Raman-induced polarization spectroscopy
2003
The potential of femtosecond Raman-induced polarization spectroscopy (RIPS) for the simultaneous determination of temperature and concentrations was investigated. These measurements were related to the rotational time response of the molecular gas mixture, which was measured as a function of the pump-probe time delay. The change of the polarizability anisotropy with respect to the vibrational levels was taken into account. The results of temperature measurements in pure CO2 showed good agreement with the values obtained by a thermocouple. The RIPS technique was also applied to a CO2-N2 gas mixture to determine simultaneously temperatures and concentrations at temperatures up to 600 K. The a…
Shaping of a ground state rotational wavepacket by frequency-chirped pulses
2001
0953-4075; A coherent rotational superposition state is produced in the ground vibronic level of N2 through the interaction of the molecule with the electric field vector of a nonresonant laser pulse. This rotational wavepacket is shaped with a linear frequency chirp of the laser field. The structural shape of the rotational coherences shows a strong dependence with the frequency-chirp amplitude. A comparison with a theoretical model allows the interpretation of the observed effects in terms of dephasing of the wavepacket induced by the laser phase distortion. Application of the presented results to the phase characterization of short XUV pulses is suggested.
Determination of concentrations in ternary and quaternary molecular gas mixtures using femtosecond Raman spectroscopy
2002
European Conference on Nonlinear Optical Spectroscopy MAR 18-19, 2002 VILLIGEN, SWITZERLAND; Measurements of concentrations in gas mixtures of three and four molecular components are presented. They rely on a femtosecond time-resolved pump-probe technique based on Raman-induced polarization spectroscopy. The rotational time response of the molecular gas mixture is measured as a function of the pump-probe time delay. No selective frequency tunability is needed as the molecular rotational spectra are excited within the laser bandwidth. The results obtained from experiments performed at room temperature in N2O-CO2-N2 and N2O-CO2-O2-N2 mixtures are presented and the accuracy of the method is di…
Development of MR active contrast agents via Parahydrogen Induced Polarization
2009
Parahydrogen Induced Polarization provides dramatic MR signal enhancement that can be exploited for molecular imaging. This method allows amongst others for Magnetic Resonance Imaging of 13C and 15N, which is usually constrained by the low MR sensitivity of these nuclei. By combining hydrogenation of barbiturates with parahydrogen under special experimental conditions (PASADENA under pressure) with a polarization transfer sequence we demonstrate the transfer of the initial 1H polarization to 13C. The polarization transfer yields a signal increase for 13C of more than 1000. Hence, the role of certain target compounds such as anesthetics like the barbituric acid derivatives could be investiga…